Red Titanite Slab - Chaos Eaters in Lost Izalith Found in a poisonous labyrinth underneath The Bed of Chaos, accessed by following a tree bridge on the right and hugging the left-hand side there will be a treasure next to a huge trap-pit. Red Titanite Chunk - Chaos Eaters in Lost Izalith Sunlight Maggots in the shortcut between Demon Ruins and Lost Izalith Black Knight(Greatsword) in Kiln of the First Flame In a chest near where you face Kalameet (PTDE). The Crystal Lizards in Great Hollow (not 100%). Titanite Slab -Extremely rare drop from Darkwraiths in New Londo Ruins Defeating Stray Demon in Undead Asylum Siegmeier of Catarina quest line ]] (only if he survives Lost Izalith with more than 50% Hp, and you save Sieglinde). Titanite Chunks - Drop from Darkwraiths in New Londo Ruins Black Knight (Sword) in Kiln of the First Flame as of patch 1.05, 2 Giant Knights near boss area in Anor Londo (this was true before 1.05 as well, just very rare) Green Titanite Shard - Crestfallen Merchant/ Giant Leech/ Slimes / Giant Blacksmith
As of 1.05 the Giant Blacksmith also sells them (3800 souls, infinite supply).
Large Titanite Shard - Crestfallen Merchant/ Slimes/ Giant Leech In Forest Hunter covenant drop for PvP kills when summoned (not 100%) Steel Knight in Painted World of Ariamis, just before Priscilla (100% droprate). One green shard gives you five normal shards. As an alternative you can also feed Kingseeker Frampt a green titanite shard, which drops from Slimes and in batches of five from Giant Leeches. Also, The Crestfallen Merchant in Sen's Fortress. Titanite Shard - Blacksmith Andre, Balder Knights in the Undead Parish, Giant Blacksmith.
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